Permethylated cycloinulohexose 1 acts, like an 18-crown-6 derivative with alkali and alkaline earth cations in organic solvents, where the cation is not bound by the central 18-crown-6 moiety, but by the upper OMe-3 groups of 1.
Y. Takai, Y. Okumura, S. Takahashi, M. Sawada, M. Kawamura and T. Uchiyama, J. Chem. Soc., Chem. Commun., 1993, 53 DOI: 10.1039/C39930000053
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