The gas-phase C6H4Br– and C6H4I– ions react with more acidic substrates than either bromo- or iodo-benzene by halide transfer rather than by proton abstraction, a behaviour consistent with an ion structure corresponding to a halide–benzyne complex.
H. V. Linnert and J. M. Riveros, J. Chem. Soc., Chem. Commun., 1993, 48 DOI: 10.1039/C39930000048
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