Synthesis of a large cavity homoleptic thioether cage and its cobalt(III) complex
Abstract
The cobalt(III) complex of the large hexathioether cage (1,9-dimethyl-3,7,11,15,18,22-hexathiabicyclo[7.7.7]tricosane) shows substantially different redox and spectral properties relative to the smaller homologous [6.6.6]icosane.