Issue 1, 1993

Synthesis, crystal and molecular structure of calcium oxo ethoxide, [Ca64-O)23-OEt)4(OEt)4]·14EtOH

Abstract

The hexanuclear complex of calcium oxo ethoxide ethanol solvate, [Ca6O2(OEt)8]·14EtOH 1 has been isolated after the prolonged refluxing of an ethanol solution of calcium ethoxide in the presence of the oxygen in air and studied by X-ray diffraction; the metal-oxygen framework is built of two [Ca4O4] cubes sharing a common [Ca2O2] face, which involves both oxo groups.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 21-23

Synthesis, crystal and molecular structure of calcium oxo ethoxide, [Ca64-O)23-OEt)4(OEt)4]·14EtOH

N. Ya. Turova, E. P. Turevskaya, V. G. Kessler, A. I. Yanovsky and Y. T. Struchkov, J. Chem. Soc., Chem. Commun., 1993, 21 DOI: 10.1039/C39930000021

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