An intense IR absorption band is observed at 298 K for dinitrogen adsorbed on copper-ion-exchanged mordenite-type zeolite, in which copper ions are exchanged in excess of the value expected from stoichiometry considerations.
Y. Kuroda, S. Konno, K. Morimoto and Y. Yoshikawa, J. Chem. Soc., Chem. Commun., 1993, 18 DOI: 10.1039/C39930000018
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