Issue 11, 1992

A dynamic NMR study of sterically hindered trialkylmethanols in the solid phase

Abstract

The temperature dependence of the 13C CP/MAS NMR spectrum of solid tri-tert-butylmethanol and three similar trialkylmethanols is reported. That energy barriers are 20–30% higher than found in solution is attributed to constraints of the lattice which also seem to cause the rotation and libration processes for these molecules to merge into a single process. The complications that may be encountered when studying dynamic NMR behaviour in solids are also discussed.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1992, 2031-2034

A dynamic NMR study of sterically hindered trialkylmethanols in the solid phase

P. J. Barrie and J. E. Anderson, J. Chem. Soc., Perkin Trans. 2, 1992, 2031 DOI: 10.1039/P29920002031

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