Using BCHPC as a source of alkoxycarbonyloxyl radical at moderate temperature in benzene or cyclohexane and in the absence of O2(under argon), the peroxydecanoic acid RCO3H is transformed into nonan-1-ol ROH in good yield. A mechanism, implying the acylperoxyl radical RCO3˙ as an intermediate, is proposed.
J. Sorba, D. Lefort, J. Fossey, F. Grisel and W. R. Sanderson, J. Chem. Soc., Perkin Trans. 2, 1992, 1565 DOI: 10.1039/P29920001565
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...