Issue 5, 1992
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Elimination–rearrangement in β-functionalised silanes—the direction of the rearrangement and its scope

Stefano Menichetti  and  Charles J. M. Stirling  

Abstract

A new eliminative rearrangement of β-silyl carbanions requires phenyl on carbon α- to silicon when the conjugate acid has a pKa(DMSO) in the range 12–30; rearrangement involves silicon and not phenyl migration.

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Article information

DOI
https://doi.org/10.1039/P29920000741
Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1992, 741-742

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Elimination–rearrangement in β-functionalised silanes—the direction of the rearrangement and its scope

S. Menichetti and C. J. M. Stirling, J. Chem. Soc., Perkin Trans. 2, 1992, 741 DOI: 10.1039/P29920000741

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