Protodesilylation of the allylsilanes 5 and 6 is selective for the formation of the exocyclic double bond isomers 7 and 8, respectively, when the group R is isopropyl, but not when it is methyl.
I. Fleming and D. Higgins, J. Chem. Soc., Perkin Trans. 1, 1992, 3327 DOI: 10.1039/P19920003327
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