Issue 23, 1992

Ring expansion by intramolecular acylation of phosphine oxides

Abstract

Alkylation of cyclic ketones with 2-Ph2PO-ethyl or 3-Ph2PO-propyl groups followed by Baeyer–Villiger oxidation and acyl transfer gives cyclic hydroxy ketones containing two or three more carbon atoms in the ring.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1992, 3169-3171

Ring expansion by intramolecular acylation of phosphine oxides

P. Wallace and S. Warren, J. Chem. Soc., Perkin Trans. 1, 1992, 3169 DOI: 10.1039/P19920003169

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