In the Lewis acid-promoted reaction between pentadienyltin (PDT) and an aldehyde, (E)-and (Z)-PDTs exhibit opposite regioreactivities: (E)-PDT reacts at the terminal ε-position and (Z)-PDT at the internal γ-position.
Y. Nishigaichi, M. Fujimoto and A. Takuwa, J. Chem. Soc., Perkin Trans. 1, 1992, 2581 DOI: 10.1039/P19920002581
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