The rate of halogen metathesis between halogenoalkanes RX 1-4(X = F, Cl, Br, I) and aqueous concentrated hydrogen halides HY (Y = Cl, Br, I) is strongly accelerated under phase-transfer catalysis conditions, without solvent. The amount and nature of the nucleophilic species in the organic phase were determined.
D. Landini, D. Albanese, S. Mottadelli and M. Penso, J. Chem. Soc., Perkin Trans. 1, 1992, 2309 DOI: 10.1039/P19920002309
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