SCHEDULED MAINTENANCE
Alkyl O-vinylcarbohydroximates, lactoxime O-vinyl ethers, and sugar lactoxime O-vinyl ethers undergo a novel thermal rearrangement to afford the corresponding 2-alkyloxazoles, 2-(ω-hydroxyalkyl)oxazoles, and oxazoles bearing a sugar moiety, respectively. This rearrangement can also occur under photochemical conditions.
M. Yokoyama, M. Irie, K. Sujino, T. Kagemoto, H. Togo and M. Funabashi, J. Chem. Soc., Perkin Trans. 1, 1992, 2127 DOI: 10.1039/P19920002127
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