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Issue 13, 1992
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β-Stereospecific hydroboration of 13-epi-pimar-8(14)-enes


β-Stereospecific hydroborations of the Δ8(14)-double bond in 13-epi-pimarenes were achieved in the absence of functional groups at C-16 or a double bond at C-15. The reaction carried out on 15,16-dihydrosandaracopimaric derivatives needed more time and a large excess of reagent due to stereochemical restrictions in the transition state.

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Article type: Paper
DOI: 10.1039/P19920001665
J. Chem. Soc., Perkin Trans. 1, 1992, 1665-1669

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    β-Stereospecific hydroboration of 13-epi-pimar-8(14)-enes

    A. S. Feliciano, M. Medarde, E. Caballero, F. Tomé and B. Hebrero, J. Chem. Soc., Perkin Trans. 1, 1992, 1665
    DOI: 10.1039/P19920001665

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