Lactones derived from D-glucose, D-mannose and L-ascorbic acid reacted unexpectedly with tris(dimethylamino)phosphine–tetrachloromethane to give, respectively, dichloroalkene, anomeric vinyl chloride or acyl chloride; this behaviour supports an ionic mechanism for the alkenation.
A. Bandzouzi, M. Lakhrissi and Y. Chapleur, J. Chem. Soc., Perkin Trans. 1, 1992, 1471 DOI: 10.1039/P19920001471
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