The synthesis of 17α-hydroxy-3β-methoxyandrost-5-ene-17β-carbaldehyde and a highly efficient method for its D-homorearrangement is described. The transformation produced by the action of ZnII afforded 17α-hydroxy-3β-methoxy-D-homoandrost-5-en-17a-one in a fast, stereospecific, and high-yield reaction.
L. Schor, E. G. Gros and A. M. Seldes, J. Chem. Soc., Perkin Trans. 1, 1992, 453 DOI: 10.1039/P19920000453
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