A spiroannulation reaction using the [2,3]sigmatropic rearrangement via a cyclic allylsulfonium ylide was developed and applied to the synthesis of (+)-acorenone B starting from (–)-perillaldehyde.
F. Kido, T. Abiko and M. Kato, J. Chem. Soc., Perkin Trans. 1, 1992, 229 DOI: 10.1039/P19920000229
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