SCHEDULED MAINTENANCE
The gas-phase pyrolysis of tri-tert-butylgallane and triisobutylgallane has been studied using infrared laser-powered homogeneous pyrolysis. Identification of products by infrared and NMR spectroscopies confirmed that the predominant reaction pathway is β-hydride elimination in both cases, but that the pyrolysis proceeds at a significantly lower temperature than that of triethylgallium.
A. S. Grady, R. E. Linney, R. D. Markwell, G. P. Mills, D. K. Russell, P. J. Williams and A. C. Jones, J. Mater. Chem., 1992, 2, 539 DOI: 10.1039/JM9920200539
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