Various derivatives of the title complexes have been synthesized and demonstrated to form stable mesomorphic phases. They provide a new family of thermotropic liquid-crystalline complexes containing a carbon–metal σ-bond and a tertiary phosphine co-ordinated to a transition metal.
T. Kaharu, H. Matsubara and S. Takahashi, J. Mater. Chem., 1992, 2, 43 DOI: 10.1039/JM9920200043
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