Issue 19, 1992
From the journal:

Journal of the Chemical Society, Faraday Transactions

Infrared investigation of the surface species obtained by chemisorption of acetylene (ethyne), C2H2 and C2D2, on high-area zinc oxide

Ghulam Hussain  and  Norman Sheppard  

Abstract

Infrared spectra from the adsorption of C2H2 and C2D2 on ZnO have been obtained between 4000 and 600 cm–1. The spectra are interpreted in terms of the presence of dissociatively adsorbed surface complexes (H—C[triple bond, length as m-dash]C–)Zn2+(OH–)(species l) and non-dissociatively chemisorbed ones (species II) of the type of a substituted ethene bonded to surface zinc ions, possibly (Z)-ZnHC[double bond, length as m-dash]CHZn. A previous ambiguity in the structural assignment of species I has been resolved.

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Article information

DOI
https://doi.org/10.1039/FT9928802927
Article type
Paper

J. Chem. Soc., Faraday Trans., 1992,88, 2927-2930

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Infrared investigation of the surface species obtained by chemisorption of acetylene (ethyne), C2H2 and C2D2, on high-area zinc oxide

G. Hussain and N. Sheppard, J. Chem. Soc., Faraday Trans., 1992, 88, 2927 DOI: 10.1039/FT9928802927

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