A bimolecular rate constant for the reactive removal of CH (X 2Π) by ketene (CH2CO) has been measured under pseudo-first-order conditions using multiphoton dissociation of CH2CO at 308 nm to generate the radicals and laser induced fluorescence to detect them. A value of (2.4 ± 0.2)× 10–10 cm3 molecule–1 s–1 was obtained at room temperature (295 ± 2 K).
G. Hancock and M. R. Heal, J. Chem. Soc., Faraday Trans., 1992, 88, 2121 DOI: 10.1039/FT9928802121
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