The hexachloroplatinic acid-catalysed hydrosilylation of vinylferrocene by octahydrosilasesquioxane H8Si8O12 to the first organometallic monosubstituted octasilasesquioxane [(η-C5H5)Fe(η-C5H4CH2CH2)]H7Si8O12 has been achieved.
G. Calzaferri and R. Imhof, J. Chem. Soc., Dalton Trans., 1992, 3391 DOI: 10.1039/DT9920003391
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