Issue 21, 1992
From the journal:

Journal of the Chemical Society, Dalton Transactions

Helical bis[2-(ferrocenylmethyleneamino)benzenethiolato] metal(II) complexes (M = Ni, Zn or Pd) and a related mercury(II) complex

Tatsuya Kawamoto  and  Yoshihiko Kushi  

Abstract

The reaction between M2+(M = Ni, Zn or Pd) and 2-(ferrocenyl)benzothiazoline in ethanol affords the trinuclear complexes [M(fabt)2][fabt = 2-(ferrocenylmethyleneamino)benzenethiolate]. Interaction of [Ni(fabt)2] or [Zn(fabt)2] with HgCl2 gives the complex trans-[Hg(fabt)2]. Infrared, 1H NMR, electronic absorption and cyclic voltammetric data are given. The crystal structures of [Ni(fabt)2] and [Pd(fabt)2] show a helical geometry, which is also confirmed for distorted-tetrahedral [Zn(fabt)2].

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Article information

DOI
https://doi.org/10.1039/DT9920003137
Article type
Paper

J. Chem. Soc., Dalton Trans., 1992, 3137-3143

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Helical bis[2-(ferrocenylmethyleneamino)benzenethiolato] metal(II) complexes (M = Ni, Zn or Pd) and a related mercury(II) complex

T. Kawamoto and Y. Kushi, J. Chem. Soc., Dalton Trans., 1992, 3137 DOI: 10.1039/DT9920003137

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