The reduction of alkyl halides by NaBH4 is efficiently catalysed by [NiL](L = dianion of 6,8,15,17-tetramethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecine), a plausible active species being [NiIL]–.
T. Arai, H. Kondo and S. Sakaki, J. Chem. Soc., Dalton Trans., 1992, 2753 DOI: 10.1039/DT9920002753
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