The rates and equilibrium constants for the reaction of aquacobalamin with iodide were measured as a function of solvent composition using methanol–water solutions. The solvent effects are consistent with a reaction that proceeds via the formation of an outer-sphere complex which is more stable for the cobalamin–methanol than for the cobalamin–water complex.
R. Moreno-Esparza, M. Lopez and K. H. Pannell, J. Chem. Soc., Dalton Trans., 1992, 1791 DOI: 10.1039/DT9920001791
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