Issue 10, 1992
From the journal:

Journal of the Chemical Society, Dalton Transactions

Oxo-, nitrido- and imido-osmium(VI) complexes with a sterically bulky chelating alkoxide ligand

Zao-Ying Li,   Wing-Yiu Yu,   Chi-Ming Che,   Chung-Kwong Poon,   Ru-Ji Wang  and  Thomas C. W. Mak  

Abstract

The synthesis and characterization of dioxoosmium(VI) complexes cis-[OsO2L] and trans-[OsO2L′](L′= NH2But, pyridine or 4-tert-butylpyridine), the nitrido complex [OsN(L)Cl], and imido complexes [OsL(NCOCF3)Cl(O2CCF3)] and [OsL(NPh)2][H2L = 2,6-bis(2-hydroxy-2,2-diphenylethyl)pyridine] are described. The crystal structures of [OsN(L)Cl] and [OsO2L(NH2But)]·0.5C6H14 have been determined: the Os[triple bond, length half m-dash]N and average Os[double bond, length half m-dash]O bond distances are 1.634(5) and 1.741(5)Å, respectively.

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Article information

DOI
https://doi.org/10.1039/DT9920001657
Article type
Paper

J. Chem. Soc., Dalton Trans., 1992, 1657-1661

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Oxo-, nitrido- and imido-osmium(VI) complexes with a sterically bulky chelating alkoxide ligand

Z. Li, W. Yu, C. Che, C. Poon, R. Wang and T. C. W. Mak, J. Chem. Soc., Dalton Trans., 1992, 1657 DOI: 10.1039/DT9920001657

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