Issue 3, 1992
From the journal:

Journal of the Chemical Society, Dalton Transactions

Reactivity of the [Re[triple bond, length half m-dash]O]3+ core toward Ph2P(Se)NH(Se)PPh2

Roberto Rossi,   Andrea Marchi,   Lorenza Marvelli,   Maurizio Peruzzini,   Umberto Casellato  and  Rodolfo Graziani  

Abstract

The salt K[N(PPh2Se)2] reacts with [ReOCl3(PPh3)2] or [AsPh4][ReOCl4] to give [ReO(Cl){N(PPh2Se)2}2]. In solution this compound tends to transform into [ReO(Cl)(Ph2PNPPh2Se)2], by loss of one Se atom from each ligand. Recrystallization from CH2Cl2–EtOH yielded [ReO(OEt)(Ph2PNPPh2Se)2] the crystal structure of which has been determined.

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Article information

DOI
https://doi.org/10.1039/DT9920000435
Article type
Paper

J. Chem. Soc., Dalton Trans., 1992, 435-437

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Reactivity of the [Re[triple bond, length half m-dash]O]3+ core toward Ph2P(Se)NH(Se)PPh2

R. Rossi, A. Marchi, L. Marvelli, M. Peruzzini, U. Casellato and R. Graziani, J. Chem. Soc., Dalton Trans., 1992, 435 DOI: 10.1039/DT9920000435

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