Issue 14, 1992

Biosynthesis of vitamin B12: structural studies on precorrin-8x, an octamethylated intermediate and the structure of its stable tautomer

Abstract

The structure of precorrin-8x, the octamethylated B12-intermediate which follows precorrin-6y in Pseudomonas denitrificans, is largely determined by 13C-labelling and NMR spectroscopy and the structure of its most stable tautomer is established.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 982-985

Biosynthesis of vitamin B12: structural studies on precorrin-8x, an octamethylated intermediate and the structure of its stable tautomer

D. Thibaut, F. Kiuchi, L. Debussche, F. Blanche, M. Kodera, F. J. Leeper and A. R. Battersby, J. Chem. Soc., Chem. Commun., 1992, 982 DOI: 10.1039/C39920000982

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