The dimethylated B12-precursor, precorrin-2 2, is prepared strongly labelled with tritium at 3-H and 8-H to allow proof that the 3-H label is retained whereas the 8-H label is lost during the biosynthetic conversion of precorrin-2 into cobyrinic acid 3.
M. Kodera, F. J. Leeper and A. R. Battersby, J. Chem. Soc., Chem. Commun., 1992, 835 DOI: 10.1039/C39920000835
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