Photochemical reaction of polynitrobenzenes with adamantylideneadamantane: the X-ray structure analysis and chemical properties of the dispiro N-(2,4,6-trinitrophenyl)-1,3,2-dioxazolidine product
Abstract
Photoreaction of polynitrobenzenes (1,3- or 1,4-dinitrobenzene; 1,3,5-trinitrobenzene) with adamantylideneadamantane gave stable dioxazolidine derivatives; X-ray structure analysis together with thermal and acid-catalysed reactions have been examined for one of the dioxazolidines.