Preparation and characterization of an oxo–iron(V)–porphyrin complex
Abstract
The novel complex OFeV(tdcpp)3, which is prepared by the addition of methanol to a methylene chloride solution of the corresponding O
FeIV(tdcpp) cation radical in CH2Cl2 at –90°C, has been characterized on the basis of UV–VIS, ESR, and deuterium NMR spectroscopy.