SCHEDULED MAINTENANCE
A new chiral metalloporphyrin (iron ‘binap capped’ porphyrin) has been synthesized and used to catalyse the asymmetric epoxidation of various unsubstituted aromatic olefins; [binap = 2,2′-bis(diphenylphosphino)-1,1′-binaphthyl].
J. P. Collman, X. Zhang, V. J. Lee and J. I. Brauman, J. Chem. Soc., Chem. Commun., 1992, 1647 DOI: 10.1039/C39920001647
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