The absolute configurations of natural goniodiol and 9-deoxygoniopypyrone are confirmed as 1 and 2 respectively by enantioselective syntheses starting from (2S,3R)-1,2-O-isopropylidene-3-(2-furyl)glycerol 6.
M. Tsubuki, K. Kanai and T. Honda, J. Chem. Soc., Chem. Commun., 1992, 1640 DOI: 10.1039/C39920001640
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