Issue 22, 1992
From the journal:

Journal of the Chemical Society, Chemical Communications

(α-Triphenylphosphonio)methylidene imido complexes of molybdenum, tungsten and rhenium: the first complexes exhibiting metal–ligand multiple-bonding with two carbon as well as two nitrogen centres

Jörg Sundermeyer,   Klaus Weber  and  Oliver Nürnberg  

Abstract

The synthesis of tetrahedral complexes [Mo(NBut)2(CHPPh3)2], [W(NBut)2(CHPPh3)2] and [Re(NBut)3(CHPPh3)] having four π-donor ligands is reported; the X-ray structure of [W(NBut)2(CHPPh3)2] reveals strong π-interactions of both imido ligands [[double bond, length as m-dash]NBut] as well as (α-triphenylphosphonio)methylidene functions [[double bond, length as m-dash]CHPPh3+], with the d0 metal centre.

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Article information

DOI
https://doi.org/10.1039/C39920001631
Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 1631-1633

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(α-Triphenylphosphonio)methylidene imido complexes of molybdenum, tungsten and rhenium: the first complexes exhibiting metal–ligand multiple-bonding with two carbon as well as two nitrogen centres

J. Sundermeyer, K. Weber and O. Nürnberg, J. Chem. Soc., Chem. Commun., 1992, 1631 DOI: 10.1039/C39920001631

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