The addition reactions of organometallic reagents to monoprotected quinone bis-epoxides 7 and quinone monoacetals 5 provide a route to the highly oxygenated cyclohexanols 2 and 3; the application of this methodology to the preparation of the aranorosin analogue 4 is described.
A. McKillop, R. J. K. Taylor, R. J. Watson and N. Lewis, J. Chem. Soc., Chem. Commun., 1992, 1589 DOI: 10.1039/C39920001589
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