Solid-state NMR spectroscopy of fast frozen samples of 15N indole labelled gramicidin A has revealed specific hydrogen bonding between the indole N–H and the solvating environment of the gramicidin channel state in the liquid-crystalline phase of hydrated lipid bilayers.
N. D. Lazo, W. Hu and T. A. Cross, J. Chem. Soc., Chem. Commun., 1992, 1529 DOI: 10.1039/C39920001529
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