Issue 20, 1992

A facile digermene-to-germylgermylene rearrangement; bulky germylene insertion into the Si–H bond

Abstract

The thermolysis of hexamesitylcyclotrigermane 1 in the presence of triethylsilane at 105 °C yields dimesityl(triethylsilyl)germane 2 and 1,1,1,2-tetramesityl(2-triethylsilyl)digermane 3; the molecular structure of 3 has been determined by X-ray crystallography.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 1484-1485

A facile digermene-to-germylgermylene rearrangement; bulky germylene insertion into the Si–H bond

K. M. Baines, J. A. Cooke and J. J. Vittal, J. Chem. Soc., Chem. Commun., 1992, 1484 DOI: 10.1039/C39920001484

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