2,3-Dithiabicyclo[2.2.1]hept-5-ene has been prepared at room temperature by the oxidation of cis-cyclopentene-3,5-dithiol and decomposes in solution at 130–160 °C to cyclopentadiene and diatomic sulfur, which has been intercepted.
T. L. Gilchrist and J. E. Wood, J. Chem. Soc., Chem. Commun., 1992, 1460 DOI: 10.1039/C39920001460
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