The title compound has been synthesised by the cleavage reaction of Ph3Pb–PbPh3 with BunLi and has been shown to have a monomeric Pb–Li bonded structure in the solid state; ab initio calculations have been used to probe the nature of the early main group metal/heavy p block metal bonding involved.
D. R. Armstrong, M. G. Davidson, D. Moncrieff, D. Stalke and D. S. Wright, J. Chem. Soc., Chem. Commun., 1992, 1413 DOI: 10.1039/C39920001413
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