Radical cyclization of epoxyketones via a 1,5-Bun3Sn group or a 1,5-H atom transfer

Sunggak Kim; Jae Suk Koh

doi:10.1039/C39920001377

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Radical cyclization of epoxyketones via a 1,5-Buⁿ₃Sn group or a 1,5-H atom transfer

Sunggak Kim and Jae Suk Koh

Abstract

Radical cyclization of epoxyketones is initiated by Buⁿ₃Sn radical addition to epoxyketones, followed by epoxide fragmentation, 1,5-H- or 1,5-Buⁿ₃Sn transfer, and cyclization.

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DOI: https://doi.org/10.1039/C39920001377
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1992, 1377-1378

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Radical cyclization of epoxyketones via a 1,5-Buⁿ₃Sn group or a 1,5-H atom transfer

S. Kim and J. S. Koh, J. Chem. Soc., Chem. Commun., 1992, 1377 DOI: 10.1039/C39920001377

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Journal of the Chemical Society, Chemical Communications

Radical cyclization of epoxyketones via a 1,5-Buⁿ₃Sn group or a 1,5-H atom transfer

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Radical cyclization of epoxyketones via a 1,5-Buⁿ₃Sn group or a 1,5-H atom transfer

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