Issue 18, 1992

Crystallographic and spectroscopic assessment of chelate-stabilized aryl halide complexes at a seven-coordinate d4 molybdenum centre

Abstract

A new series of chelate stabilized aryl halide coordination complexes of molybdenum are prepared by a novel oxidative addition strategy; quantitative equilibrium measurements suggest that the structure of the chelate ring, rather than the identity of the halide (X = Cl, Br, I), controls the strength of aryl halide binding in these complexes.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 1374-1376

Crystallographic and spectroscopic assessment of chelate-stabilized aryl halide complexes at a seven-coordinate d4 molybdenum centre

R. Harrison, A. M. Arif, G. Wulfsberg, R. Lang, T. Ju, G. Kiss, C. D. Hoff and T. G. Richmond, J. Chem. Soc., Chem. Commun., 1992, 1374 DOI: 10.1039/C39920001374

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