Issue 18, 1992

A convenient synthesis of (E)-β-ethoxycarbonylvinylsilanes by palladium-catalysed regio- and stereo-specific hydroesterification of trimethylsilylacetylenes

Abstract

Palladium-catalysed hydroesterification of trimethylsilylacetylenes 1 gives (E)-β-ethoxycarbonylvinylsilanes 2 exclusively in excellent yields.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 1358-1359

A convenient synthesis of (E)-β-ethoxycarbonylvinylsilanes by palladium-catalysed regio- and stereo-specific hydroesterification of trimethylsilylacetylenes

R. Takeuchi, M. Sugiura, N. Ishii and N. Sato, J. Chem. Soc., Chem. Commun., 1992, 1358 DOI: 10.1039/C39920001358

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