The interaction of tris(β-ketoenolato)cobalt(III) complexes with protic acids results in a ligand–metal electron transfer with the formation of a variety of β-ketoenolyl radicals that can be detected by ESR spectroscopy.
P. Diversi, C. Forte, M. Franceschi, G. Ingrosso, A. Lucherini, M. Petri and C. Pinzino, J. Chem. Soc., Chem. Commun., 1992, 1345 DOI: 10.1039/C39920001345
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