Issue 18, 1992

Synthesis of a stable sulfenic acid, trans-decalin-9-sulfenic acid

Abstract

Hydrolysis of trans-9-decalyl methoxymethyl sulfoxide with 7% perchloric acid in MeOH–H2O (2 : 1) gave crystalline trans-decalin-9-sulfenic acid whose structure was confirmed by IR, NMR and mass spectrometry; addition to methyl propiolate affording methyl trans-3-(trans-9-decalylsulfinyl)acrylate.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 1337-1338

Synthesis of a stable sulfenic acid, trans-decalin-9-sulfenic acid

T. Yoshimura, E. Tsukurimichi, S. Yamazaki, S. Soga, C. Shimasaki and K. Hasegawa, J. Chem. Soc., Chem. Commun., 1992, 1337 DOI: 10.1039/C39920001337

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