Coordination polymerisation of a binuclear copper(II) macrocyclic cation through self-assembly
Abstract
The newly prepared binuclear cation [Cu2Cl(L)]3+[L= 6,6′-spiro-bi(cyclam) where cyclam = 1,4,8,11-tetraazacyclotetradecane] self-assembles into a µ-chloro-bridged one-dimensional polymer; the crystal structure and preliminary spectroscopic features are reported.