Ab initio calculations show that electropositive substituents such as silyl groups have a remarkable effect on the relief of strain from polycyclic silicon compounds, the same effects being predicted also for the still heavier polycycles.
S. Nagase, K. Kobayashi and M. Nagashima, J. Chem. Soc., Chem. Commun., 1992, 1302 DOI: 10.1039/C39920001302
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