A novel and efficient synthesis of tricyclopentanoids via inverse demand π4s+π2s cycloaddition and photochemical reaction of annulated[2.2.2]octenones having an α-alkoxy-β,γ-unsaturated carbonyl chromophore, is described.
V. Singh and B. Thomas, J. Chem. Soc., Chem. Commun., 1992, 1211 DOI: 10.1039/C39920001211
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