A model based on π-facial asymmetry in the calculated molecular electrostatic potentials is proposed to account for chromatographic behaviour of phaclofen 1 and its fluorinated derivatives 2–4 on a chiral cyclodextrin stationary phase.
P. Camilleri, A. J. Edwards, H. S. Rzepa and S. M. Green, J. Chem. Soc., Chem. Commun., 1992, 1122 DOI: 10.1039/C39920001122
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