Vinyldichloroboranes react with 1,3-dienes and the sequence Diels–Alder cycloaddition–reductive alkylation of benzyl azide leads directly to secondary amines, therefore, showing that vinyldichloroboranes behave as synthetic equivalents of secondary enamines of defined stereochemistry.
N. Noiret, A. Youssofi, B. Carboni and M. Vaultier, J. Chem. Soc., Chem. Commun., 1992, 1105 DOI: 10.1039/C39920001105
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