Photoinduced axial bond exchange reaction of dichlorophosphorus(V)tetraphenylporphyrin chloride: photochemical activation of central three-centre four-electron bond through the σ–π interaction
Abstract
A novel photoinduced axial bond exchange reaction of dichlorophosphorus(V)tetraphenylporphyrin chloride in various alcohols affords axial dialkoxyphosphorus(V)tetraphenylporphyrin derivatives.